Plasma-etching

Plasma etching technology from Moorfield is used for for Soft Etching of sensitive materials, reactive ion etching (RIE) and for substrate cleaning. The technology is available packaged into dedicated nanoETCH tools or in combination with other hardware inside larger MiniLab process chambers and load-locks.

Soft Etching

Moorfield’s Soft Etching technology was developed in collaboration with the Nobel Prize-winning graphene group at Manchester University, UK. Headed by Prof. Andre Geim, the group received their first system from Moorfield when they started their 2D materials research over 10 years ago. Since then, the technology, implemented within our compact nanoETCH range, has become a critical part of all experimental work. They now have 3 tools, housed within the National Graphene Insitutute (NGI). There is also another tool at the Graphene Engineering Innovation Centre (GEIC) — also in Manchester.

Soft Etching technology is optimised for providing the fine control required for substrate and device preparation in graphene and 2D materials research:

  • Substrate preparation for mechanical exfoliation: When preparing 2D material ‘flakes’ via mechanical exfoliation (also known as the sticky-tape method), the nature of the substrate surface is crucial. Soft Etching tools are now being used to obtain the topological and chemical substrate surface properties necessary for producing large flake areas.
  • 2D material patterning: Given their thinness, 2D materials are fragile and require finely-controlled etching conditions for device fabrication. Soft Etching technology provides this control and also allows for patterning without cross-linking common mask photoresists (e.g., PMMA).
  • Defect engineering: A key research theme for graphene science is defect engineering. Through controlled low plasma-powers, soft-etching technology is being used for creating point defects in lattices for implementing control over this aspect of the material. Fine control is necessary for reproducible results and to avoid uncontrolled material destruction.

As well as 2D materials, Soft Etching technology has found numerous other applications. For example, it has been used for precision removal of alternative resists such as PPA and for the tuning of hydrophobicity of glass slides prior to wet depositions.

Soft Etching is available within our nanoETCH and MiniLab platforms.

SF6 and CHF3 Etching

While the etching of 2D materials can be done through the careful application Ar and/or O2 plasmas, other materials more commonly targeted by RIE require a more aggressive approach. For this, Moorfield etching technology has recently been enhanced to provide for the use of the fluorine-chemistry etchants SF6 and CHF3. To allow for this, both hardware and software have been upgraded in line with the demands these process gases introduce.

Some examples of applications are:

  • h-BN sidewalls: A pit was etched into a multi-layer stack of h-BN, using Moorfield etching technology contained within a MiniLab 026. With SF6 as the etchant gas and a Soft Etching approach, just 7–8 layers of material were removed during a 2 minute process. Residual roughness at the bottom of the pit was just 1 atomic layer.
  • h-BN bulk etching: By changing conditions, much higher etch rates were possible. Users were able to achieve an etch depth of 130 nm at a rate of 1.1 nm/s.
  • SiO2 etching: A thermally oxidised Si wafer was etched using a nanoETCH tool using CHF3 as etchant gas. An ultra-low etch rate of ~1.3 Å/s was obtained, allowing for excellent control.

Fluorine-chemistry etching is available within our nanoETCH and MiniLab platforms.

Pre-Deposition Cleaning

A requirement for many phycial vapour deposition (PVD) processes is pre-cleaning of substrates. An effective method for this is to create reactive plasmas in close proximity to substrate surfaces, leading to the removal of unwanted contaminants. Moorfield, as a leading supplier of R&D deposition tools now routinely fit systems with etching stages that provide this functionality.

Etching stages can be fitted into a process chamber in combination with the deposition substrate stage itself (the stage is first active for etching, then for deposition). However, where psosible, it is best to position the cleaning stage in a supporting load-lock as this confines removed material away from the process and also allows for equipping of the main deposition stage with hardware not compatible with plasma etching.

Pre-deposition etch cleaning is available in our MiniLab PVD tools.

Technical notes about Plasma-etching:

An introductory explanation of substrate adhesion, and how this can be improved….
Moorfield graphene soft-etching technology allows for the controlled removal of graphene and 2D materials, without cross-linking photoresists that can lead to residual contamination that…

Moorfield systems for Plasma-etching:

The MiniLab range from Moorfield: Flexible, modular PVD systems for high-quality R&D and pilot-scale production….
MiniLab 026 systems are compact floor standing vacuum evaporators with easy-access ‘clam-shell’ chambers. Suitable for metal, dielectric and organics deposition via evaporation and sputtering…
nanoETCH systems implement Moorfield’s unique Soft Etching technology and provide the fine control crucial for numerous etching applications including graphene, 2D materials and many…

Recent news posts about Plasma-etching:

Due to steadily increasing demand, Moorfield have released a new standalone website just for sputter targets! As industry leaders in high-vacuum PVD, CVD, and…
Plasma etching is an excellent way to clean substrate surfaces, promote adhesion and optimise sample quality layers…
Research-grade vacuum deposition with inert sample handling…
Moorfield Nanotechnology Limited (Knutsford, UK) recently announced the appointment of a new distributor for their PVD, CVD and etch products for the Australia and…
Researchers at the University of Cambridge and Nokia Research Centre have used Moorfield’s nanoETCH to carefully ‘damage’ single graphene sheets in order to minimise contact resistances…
Sassi, U., et al. Nature Communications 2017 DOI: 10.1038/ncomms14311 This work reports the use of graphene as part of an uncooled, mid-infrared photodetector, where…
This time we took our nanoETCH and nanoPVD systems along to Paris, Caen and Toulouse for some live product demonstrations. Thank you to everyone…
With all its unique features and capabilities, the nanoETCH is a featured product in the most recent Physik Journal (published by Wiley in Germany)….
Another month, another demo tour! This time, up to the north-east UK. Thanks to all who came along to live demonstrations of our nanoETCH and nanoCVD products for…
Moorfield are planning their latest demo tour. This time we’ll be heading to the English West Country and South Wales. We’ll be bringing nanoETCH…
If you’re off to Graphene 2016 next week, come find us at booth 3 in the exhibition. Working nanoCVD-8G and nanoETCH tools on display!…
Together with our Italian distributor 2M Strumenti, we will be exhibiting our unique benchtop graphene synthesis and etching products at Graphene 2016, in Genoa, 19-22 April. Come along and…

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